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Choose whichever timing you can maintain consistently without side effects

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As you can probably tell from the name, glutamic acid makes glutathione an acid, and there is not a corresponding basic amino acid (lysine or arginine) in glutathione to neutralize it

8.2 Summary of RCTs Early studies using low-dose NAC (200 mg TID) showed no significant benefit over placebo in PEFR, weight, antibiotic use, cough, sputum viscosity, or symptom perception (102)